organometallic, magnetic, carbon materials, tungsten bronze
A Taiwanese team isolated and crystallised the first terminal nickel–oxygen complex on an unsymmetrical β-diketiminate ligand (Ni–O 1.750 Å), confirming the bond by ¹⁸O isotope-labelled resonance Raman on the MRID (532 nm).
Swapping Cs for Rb for K systematically distorts the WO6 framework of a NIR-shielding tungsten bronze — mapped by single-crystal X-ray and RAMaker Raman.
Raman D/G analysis showed microwave treatment in CO reduces defect density in Co/SiO2-loaded carbon nanotubes — a ProTrusTech co-authored fuel-cell study.
An independent Analytical Chemistry study validated a new IR photoacoustic method for carbon materials against Raman fingerprints taken on ProTrusTech’s MRI.
One research team, one carbon-shell trick, two magnetic oxides — and two opposite electronic mechanisms, both confirmed with RAMaker Raman spectroscopy.
Swapping one ortho-substituent shifted Cu···Cu distances from 2.75 Å (bonded) to 3.59 Å (no interaction) across a nine-ligand tricopper(I) series — proof that sterics, not electronics, control these cuprophilic interactions.
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